Condensation Approach to Aliphatic Oligourea Foldamers: Helices with N‐(Pyrrolidin‐2‐ylmethyl)ureido Junctions
Identifieur interne : 002575 ( Main/Exploration ); précédent : 002574; suivant : 002576Condensation Approach to Aliphatic Oligourea Foldamers: Helices with N‐(Pyrrolidin‐2‐ylmethyl)ureido Junctions
Auteurs : Juliette Fremaux [France] ; Lucile Fischer [France] ; Thomas Arbogast [France] ; Brice Kauffmann [France] ; Gilles Guichard [France]Source :
- Angewandte Chemie [ 0044-8249 ] ; 2011-11-25.
English descriptors
- Teeft :
- Aliphatic oligourea foldamers, Aliphatic oligoureas, Angew, Chem, Convergent condensation, Crystal structures, Foldamers, Guichard, Helical, Helical structure, Helix, Long helical segments, Main chain, Oligourea foldamers, Oligoureas, Proline, Proline residues, Pyrrolidine, Pyrrolidine junction, Pyrrolidine ring, Pyrrolidine unit, Pyrrolidine units, Segment junctions, Short oligoureas, Succinimidyl carbamate, Urea, Verlag gmbh, Weinheim angew.
Abstract
Eine einfache Kupplungsstrategie führt effizient zu aliphatischen Oligoharnstoff‐Foldameren. Kristallstrukturanalysen belegen, dass die Pyrrolidin‐Einheiten (rot; siehe Bild) die Faltung der Oligoharnstoff‐Helices nicht beeinträchtigen. Die modulare Strategie öffnet einen Zugang zu langen Helixstrukturen mit nicht benachbarten Pyrrolidin‐Einheiten, etwa in der Synthese einer ungefähr 40 Å langen Helix.
Url:
DOI: 10.1002/ange.201105416
Affiliations:
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Le document en format XML
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<front><div type="abstract" xml:lang="de">Eine einfache Kupplungsstrategie führt effizient zu aliphatischen Oligoharnstoff‐Foldameren. Kristallstrukturanalysen belegen, dass die Pyrrolidin‐Einheiten (rot; siehe Bild) die Faltung der Oligoharnstoff‐Helices nicht beeinträchtigen. Die modulare Strategie öffnet einen Zugang zu langen Helixstrukturen mit nicht benachbarten Pyrrolidin‐Einheiten, etwa in der Synthese einer ungefähr 40 Å langen Helix.</div>
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